28. Li, H.; Shen, S.-J.; Zhu, C.-L.; Xu, H.* “Direct Intermolecular AntiMarkovnikov Hydroazidation of Unactivated Olefins” J. Am. Chem. Soc. 2019. DOI: 10.1021/jacs.9b04381


27. Li, H.; Shen, S.-J.; Zhu, C.-L.; Xu, H.* “Enantioselective Synthesis of Oseltamivir Phosphate (Tamiflu) via the Iron-Catalyzed Stereoselective Olefin Diazidation.” J. Am. Chem. Soc. 2018. DOI: 10.1021/jacs.8b06900

26. Zhu, C.-L.; Wang, C.; Qin, Q.-X.; Yruegas, S.; Martin, C. D.; Xu, H.* “Iron-Catalyzed Olefin Azido-Trifluoromethylation for Vicinal Trifluoromethyl Amine Synthesis” ACS Catal. 2018, 8, 5032.

25. Shen, S.-J.; Zhu, C.-L.; Lu, D.-F.; Xu, H.* “Iron-Catalyzed Direct Olefin Diazidation via Peroxyester Activation Promoted by Nitrogen-Based Ligands” ACS Catal. 2018, 8, 4473.

24. Zhu, H.-T.; Arosio, L.; Villa, R.; Nebuloni. M.;* Xu, H.* “Chemical Process Safety Assessment of the Iron-Catalyzed Direct Olefin Diazidation for Expedient Synthesis of Vicinal Primary Diamines” Org. Process Res. Dev. 2017, 21, 2068.

Comments from Chemical and Engineering News: Azides safely used to synthesize diamines.


TOC aminofluorination jpeg
Scheme 1
Table of Content diazidation modified for proposal

18.  Lu, D. F.; Zhu, C. L.; Jia, Z. X.; Xu, H.* “Iron(II)-Catalyzed Intermolecular Amino-Oxygenation of Olefins through the N-O Bond Cleavage of Functionalized Hydroxylamines” J. Am. Chem. Soc. 2014, 136, 13186.


Scheme 1
highlight Sept 20
TOC revised
Postdoctoral Research
9.  Gerard, B.; O’Shea, M. W.; Donckele, E.; Kesavan, S.; Akella, L. B.; Xu, H.; Jacobsen, E. N.; Marcaurelle, L. A. “Application of a Catalytic Asymmetric Povarov Reaction using Chiral Ureas to the Synthesis of a Tetrahydroquinoline Library.” ACS Comb. Sci. 2012, 14, 621.
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